March 2005
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Report on Hydrogen and Fuel Cell Safety Published
by Karen Hall
Vice President, Technical Operations of the National Hydrogen Association

Fuel Cell Today (www.fuelcelltoday.com) has recently published a report on hydrogen and fuel cell safety by Vicki P. McConnell, Editor of the Fuel Cell Industry Report Newsletter (www.FcellReport.com). Finding Safe Haven in Hydrogen and Fuel Cell Systems was published in two parts. It attempts to put hydrogen safety into perspective, and uses information provided by manufacturers and safety experts interviewed specifically for the report in recent months. The article examines hydrogen myths, and describes engineering protocols being used to assure safety in hydrogen and fuel cell systems today. The report utilizes information from the NHA's Hydrogen Safety Factsheet, as well as an analysis of safety precautions and lessons learned from industry.

A synopsis is provided here. The purpose of this synopsis is informational only. Please refer to the full report for references, accompanying graphics, and many resources for hydrogen and fuel cell safety and education.

Original equipment manufacturers (OEMs) are keenly aware that H2 must be proven as a safe fuel on par with proving reliability, longevity, ease of maintenance, and low cost in commercial fuel cell products. To that end, emphasis on safety is part and parcel of evolving fuel cell system designs from OEMs, along with intensive system testing. Likewise, safety is central to efforts by fuel cell industry organisations, codes and standards bodies, and world governments (though this report focuses primarily on efforts in the United States).

Every element of a fuel cell system will have its own safety assessment prior to widespread commercialisation. For the purposes of this report, a fuel cell system encompasses these elements:

  • The stack (supplying primary power, made from graphite, ceramic, metal, or composite and containing the catalyst that begins the electrochemical reaction between H2 and oxygen needed in every fuel cell)

  • Balance of plant (BOP, comprised of auxiliary components that may include a heat exchanger, pumps, fans and blowers, motors and compressors, humidification and water management components, controllers, inverters and converters, filters, valves, piping, flow meters, seals and gaskets and more)

  • Fuel processor or reformer (when using methods such as steam, autothermal or partial oxidation to extract H2 from a feedstock fuel other than H2)

  • Fuel storage (such as variously-sized high pressure or cryogenic tanks, or solid storage forms such as hydrides) on vehicles or at stationary locations, and small, replaceable pressurised or nonpressurised cartridges in portable devices)

  • Fuel (H2 in compressed, liquid or solid form; also hydrocarbon reformate fuels such as gasoline, diesel, natural gas, propane, and kerosene from which H2 is derived; synthetic fuels that also produce H2; or on-demand fuels such as sodium
    borohydride/water that are inert until combined with the aid of a catalyst to create H2).

  • The basic properties of H2 as an energy carrier can be seen in light of a need for safety in handling it, as well as by the benefits this carrier provides within fuel cell systems. For a hydrogen safety overview, please may view the National Hydrogen Association's "Hydrogen Safety" fact sheet (216Kb PDF).
Though FCVs represent one of the potential high volume markets, transportation application of fuel cells still appears to have the longest timeline to commercialisation (at least the year 2020 by some estimations). They also require perhaps the most complex integration of a fuel cell system. As described by the California Fuel Cell Partnership (CaFCP), "a fuel cell engine is the complete set of components that integrate with a fuel cell to form a small energy plant that creates electricity to power a vehicle's wheels."
The well known benefits of H2 powered FCVs boil down to near zero pollution, except for exhaust water vapor, and zero production of greenhouse gases due to a lack of combustion and increased energy efficiencies. FCVs can also contribute to reducing noise pollution. At their most productive, FCVs could be used as backup power systems for residential or business electricity.

The consensus among industry, government, academia, and other hydrogen and fuel cell experts is this: Overall safety concerns have effectively remained the same as those identified 5-10 years ago, although we know more and have better data from these additional years of hands-on hydrogen experience, and a much higher degree of safety and confidence. The use of hydrogen as an energy carrier in applications including fuel cell vehicles deserves the same, but not inordinately more, attention to safety as with other fuels and vehicle propulsion systems. The potential safety issues for hydrogen are different, and these differences must be factored into design with absolute rigor, as required for any safe and reliable energy or vehicle fuel system.

The report focuses on the commercialization of fuel cell vehicles, and cites reports from the CaFCP, University of Miami, and others that describe results of modeling and testing for use of fuel cell vehicles in normal conditions, including garages.

Over the past five years, one of the crucial issues that has emerged at the core of achieving a hydrogen economy with FCVs is the need for a global infrastructure of fueling stations. Concepts continue to fly thick and fast as to the best way to create this infrastructure (Will entirely new stations be required, or can existing stations be adapted? How fast can codes and standards bodies and OEMs conduct the testing necessary to be sure H2 is safe in these stations?). Also in question is the expense of a hydrogen infrastructure. Some believe billions will be have to be spent. (Others believe there are technological answers that will not require entirely new stations to be built, but will provide the means to adapt existing stations.)

Moreover, in the last two years, major "hydrogen highway," "hydrogen corridor," and "hydrogen village partnership" initiatives began in the US, Canada, Europe, Iceland, Japan, and Norway. As with each FCV, each of these fueling stations and fueling station networks will go through a stringent safety assessment and risk management siting review that must include cooperation from relevant jurisdictional bodies.

From sophisticated and complex internal combustion engines in current vehicles, to furnaces, ice rinks, refrigerators, barbeques and toasters, people are already operating equipment every day that entails particular safety concerns. This equipment and relevant energetic fuels are accepted for proven safety, in large part because they have been tested and certified to applicable codes and standards for consumer use. The same or higher levels of testing and certification are underway for fuel cell systems.

Virtually every OEM who participated in this report is working on codes and standards formation, and have also availed themselves of third party certification, often in both the U.S. and abroad. "Participation on code and standard committees provides the opportunity to discuss and resolve potential issues with other technical experts," observes Glenn Scheffler, Manager of General Engineering for UTC Power in South Windsor, CT, USA. "This creates a core group with common understanding of how to safely manage situations involving design, fabrication and use of fuel cell products."

Plug Power's (Latham, NY, USA) Director of Government Relations, George Earle, comments that participation in codes and standards formation groups offers the opportunity to review codes that may have a dated genesis, and rectify that by encompassing more current specific and relevant scenarios. And Honda's Manager of Fuel Cell Vehicles, Sales and Marketing, Stephen Ellis (Torrance, CA, USA) takes the view that codes and standards committees allow a degree of harmonisation, especially among automakers who don't always agree with each other's perspective. He adds that committee participation is extending beyond just R&D representatives with a mostly technical outlook, to sales and marketing. "Now that my opinion is being sought, that tells me industry wants to get it right in the eyes of the end user."

Indeed multiple codes and standards bodies have task groups working internationally on testing and certification requirements for meeting existing and creating new codes, standards, and best practices for operating fuel cell systems. This is true whether the fuel cell system is applied to stationary, portable or transportation applications.

The report also describes many codes, standards, and recommended practices specific to fuel cells that are beginning to be published, as well as research activities through DOE and DOT/ NHSTA.

The U.S. hydrogen and fuel cell industries are addressing the public's concern about hydrogen and fuel cell safety through the development of standards, codes and certification requirements, as well as through education and outreach programs.

The fuel cell industry as a whole must continue to take an active role in designing codes and standards for fuel cells and H2-related products. Promoting those testing standards within numerous customer industries will help them understand that the products are safe. Proof of performance in customer applications is just as important. After all, if the public perceives H2 as unsafe, there will be no general acceptance of fuel cell products. So it takes everyone involved in both the fuel cell and H2 industries to educate customers, government entities, and the public about the safety of these products.

The report cites the US DOE, DOT, National Renewable Energy Laboratory (NREL), and National Hydrogen Association (NHA) as entities involved in "preparing customers for fruitful dialogues with the authorities having jurisdiction regarding H2 and the safety elements of its use in a product or fueling facility."

Just as important as assuring the public that fuel cells and H2 can be operated safely in their communities, is assurance for the emergency responders -- typically fire, police, and other rescue personnel -- that handling a H2 incident can be accomplished with adequate training and without undue threat to personal safety. The challenge will be not just at the federal level with new codes and standards related to H2 storage, but in training all the fire marshals and personnel in individual municipalities, at the local level. A wide segment of responder personnel must be trained to handle H2.

"By itself, attention to safety cannot draw H2 into the marketplace, but if poorly addressed, it will pose a formidable barrier," states the US National Research Council's Committee on Alternatives and Strategies for Future H2 Production and Use in "The Hydrogen Economy -- Opportunities, Costs, Barriers and R&D Needs." Clearly the sources for this report are active participants in properly addressing the safety of H2 and fuel cells. "I think it's critically important that regulatory bodies and the public be shown definitively that H2 is in fact a safe and reliable fuel," concludes Idaho National Laboratory's John Kolts. "This is more than just perception, but a demonstrable level of safe performance. I also believe those of us in the H2 development community are responsible for this demonstration of safe H2 use in safe fuel cell products."

Air Products' Jim Hansel concludes "the key safety issues have been addressed. I believe that the main issue is to get properly designed units out into properly designed facilities, with OEMs and educated customers operating these properly. This way, public acceptance will be gained on its own."

To read this two-part report, please click below.

Finding Safe Haven in Hydrogen and Fuel Cell Systems
Part 1

Finding Safe Haven in Hydrogen and Fuel Cell Systems
Par
t 2

For more information on Fuel Cell Industry Report, a monthly subscriber-based newsletter, visit www.FcellReport.com. Ms McConnell can be reached at Vmcconnell@FcellReport.com.