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Industry Input Needed for NWIP: Hydrogen Quality for Fuel
Cells
by Karen Hall
Vice President, Technical Operations of the National Hydrogen
Association
As many of you know, ISO TC 197 WG 12 is developing a new
Technical Specification for PEM fuel cells for road vehicles.
The existing ISO 14687:1999 Hydrogen fuel - Product specification
has been deemed inappropriate as it allows constituent concentrations
that may harm the fuel cell. The working group had been considering
removing all fuel cell applications from the standard, however
it was decided that was outside the scope of WG12. This action
is now being pursued seperately. The NHA has agreed to work
with the US Fuel Cell Council to create a new work item proposal
for consideration by the US TAG that seeks to ammend ISO 14687
so that it will not apply to fuel cell applications that are
also deemed inappropriate for the grades of hydrogen contained
in this standard. To do this, we are seeking industry feedback.
We are asking you to review the specification in the table
below, which is intended to be applied to hydrogen fuel as
produced and delivered. In order to gather information to
scope and justify a New Work Item Proposal, we are asking
interested parties to answer the following questions:
- What type of fuel cell are you considering?
- What is the application (stationary, transportation mobility,
auxillary power units, portable, etc.)?
- Do you have any applications for fuel cells for transportation
other than PEM fuel cells for road vehicles, such as auxillary
power units? If so, please describe:
- Do you currently use, or plan to use, ISO 14687 to specify
the hydrogen fuel for your application?
- What standard(s) or specification(s) are used currently
for specifying the hydrogen for your fuel cell application(s)?
- Do you have any concerns with the specifications as presented
in Table I, below?
- Is your concern with gaseous hydrogen, liquid hydrogen,
or both?
- Please describe what you feel should be changed in the
existing standard to address your concerns.
- If a New Work Item Proposal is approved, would you like
to be considered as a technical expert for the resulting
new ISO TC 197 Working Group?
- Your name, job title, company, and contact information.
The NHA will collect the industry feedback to draft a New
Work Item Proposal. Please email your feedback to hallk@hydrogenassociation.org.
For the following table, the types and grades of hydrogen
fuel specified relate to the form of hydrogen and the limiting
characteristics of constituents (maximum contamimant levels).
Please note that this table is not to be used as a standard
or specification. It represents a combination of requirements
in the published ISO standard and proposed modifications being
considered by WG12, but not yet approved by ISO TC 197. It
also does not contain all the information contained in the
published standard, such as specifications for slush hydrogen.
The information contained is limited to the purpose of identifying
concerns for gaseous or liquid hydrogen for fuel cell applications.
It is provided only to seek industry feedback as to its suitability
for various fuel cell applications. For complete specifications,
please see the published standard, ISO 14687:1999 Hydrogen
fuel - Product specification, which can be purchased from
ISO, ANSI, and other national standards adoption organizations.
Type I, grade A gaseous hydrogen fuel for internal combustion
engines for transportation; residential/commercial appliances
(this could include fuel cells);
Type I, grade B gaseous hydrogen for industrial fuel, for
use e.g. in power generation or as a heat energy source (this
could include fuel cells);
Type I, grade C gaseous hydrogen fuel for aircraft and space-vehicle
ground support systems (this could include fuel cells);
Type II, grade C liquid hydrogen fuel for aircraft and space-vehicle
onboard propulsion and electrical energy requirements (this
could include fuel cells); internal combustion engines for
land vehicles.
Table 1 - Directory of limiting characteristics
Dimensions in micromoles per mole unless otherwise
stated
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Characteristics
(assay)
|
Type I
|
Type II
|
|
Hydrogen purity (minimum mole fraction,
%)
|
98.0
|
99.90
|
99.995
|
99.995
|
| Para-hydrogen (minimum
mole fraction, %) |
NS
|
NS
|
NS
|
95.0
|
Impurities
(maximum content) |
| Total gases |
-
|
-
|
50
|
50
|
| Water (cm3/m3) |
NCa
|
NC
|
b
|
b
|
| Total hydrocarbon |
100
|
NC
|
b
|
b
|
| Oxygen |
a
|
100
|
c
|
c
|
| Argon |
a
|
-
|
c
|
c
|
| Nitrogen |
a
|
400
|
b
|
b
|
| Helium |
-
|
-
|
39
|
39
|
| CO2 |
-
|
-
|
d
|
d
|
| CO |
1
|
-
|
d
|
d
|
| Mercury |
-
|
0.004
|
-
|
-
|
| Sulfur |
2.0
|
10
|
-
|
-
|
| Permanent particulates |
f
|
e
|
e
|
e
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NOTE 1 NS: Not specified
NOTE 2 NC: Not to be condensed
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a Combined water, oxygen, nitrogen
and argon: max. 1 900 µmol/mol.
b Combined nitrogen, water and hydrocarbon:
max. 9 µmol/mol.
c Combined oxygen and argon: max. 1 µmol/mol.
d Total CO2 and CO: max. 1 µmol/mol.
e To be agreed between supplier and customer.
f The hydrogen shall not contain dust, sand, dirt, gums,
or other substances in an amount sufficient to damage
the fueling equipment or the vehicle (engine) being fueled
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